used lithium electrodeposition in tetrahydrofuran to synthesize ammonia at more moderate pressures with reasonable Faradaic efficiency. [58][59] It was isolated again by Peter Woulfe in 1767,[60][61] by Carl Wilhelm Scheele in 1770[62] and by Joseph Priestley in 1773 and was termed by him "alkaline air". If the process of creating it can be scaled up via purely renewable resources, producing green ammonia, it could make a major difference in avoiding climate change. My aim is to create a basic buffer solution. Lower ambient temperatures reduce the rate of algal photosynthesis so less ammonia is removed by any algae present. Language links are at the top of the page across from the title. Ammonia is commonly used in the illegal manufacture of methamphetamine through a Birch reduction. Within an aquaculture environment, especially at large scale, there is no fast-acting remedy to elevated ammonia levels. [16] In 2021 this was 235 million tonnes, with very little being made within the United States. The gas is flammable (autoignition temperature: 651C) and can form explosive mixtures with air (1625%). A step-by-step explanation of how to draw the NH3 Lewis Dot Structure (Ammonia).For the NH3 structure use the periodic table to find the total number of vale. Ammonia (also called azane) is a compound of Hydrogen and Nitrogen with a molecular formula NH 3. NH3 + H2O NH4OH. Most studies involving liquid ammonia solutions are done in reducing conditions; although oxidation of liquid ammonia is usually slow, there is still a risk of explosion, particularly if transition metal ions are present as possible catalysts. The maximum concentration of ammonia in water (a saturated solution) has a density of 0.880 g/cm3 and is often known as '.880 ammonia'. 0.00192 is 0.937 percent of 0. . A saturated solution of ammonium nitrate (Divers' solution, named after Edward Divers) contains 0.83mol solute per mole of ammonia and has a vapour pressure of less than 1bar even at 25C (77F). / For example, lithium dissolves in liquid ammonia to give a blue solution (solvated electron) of lithium amide: Like water, liquid ammonia undergoes molecular autoionisation to form its acid and base conjugates: Ammonia often functions as a weak base, so it has some buffering ability. United States Department of Transportation, "Rapid growth of new atmospheric particles by nitric acid and ammonia condensation", "Cutting-Edge Solutions For Coking Wastewater Reuse To Meet The Standard of Circulation Cooling Systems", "Ammonia in Groundwater, Runoff, and Streams", "The Management of Ammonia Levels in an Aquaculture Environment", "Ammonia Tanks - Carbon and Stainless Steel Construction", "Nitrogen Statistics and Information U.S. Geological Survey", "Nobel Prize in Chemistry (1918) HaberBosch process", "Chemistry of the Group 2 Elements Be, Mg, Ca, Sr, Ba, Ra", Ullmann's Encyclopedia of Industrial Chemistry, "Green ammonia electrolysis breakthrough could finally kill Haber-Bosch", "FuelPositive promises green ammonia at 60% the cost of today's gray", "Elektrolytische Bindung von komprimiertem Stickstoff bei gewhnlicher Temperatur", "Lithium-mediated electrochemical reduction of high pressure N2 to NH3", "Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction", "A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements", "Non-aqueous gas diffusion electrodes for rapid ammonia synthesis from nitrogen and water-splitting-derived hydrogen", "Nitrogen reduction to ammonia at high efficiency and rates based on a phosphonium proton shuttle", "eMedicine Specialties > Metabolic Diseases > Hyperammonemia", "Nitrogen Fixation and Inoculation of Forage Legumes", NASA's Solar Exploration: Multimedia: Gallery: Gas Giant Interiors, "Ammonia and cyanoacetylene observations of the high-density core of L-183 (L-134-N)", "Branching fractions of dissociative recombination of NH4+ and NH2+ molecular ions", "Comprehensive models of diffuse interstellar clouds Physical conditions and molecular abundances", "Observations of Ammonia in External Galaxies I. NGC 253 and M 82", Emergency Response to Ammonia Fertilizer Releases (Spills), National Institute for Occupational Safety and Health Ammonia Page, NIOSH Pocket Guide to Chemical Hazards Ammonia, https://en.wikipedia.org/w/index.php?title=Ammonia&oldid=1148294390, Short description is different from Wikidata, Pages using collapsible list with both background and text-align in titlestyle, Wikipedia articles needing clarification from December 2022, Articles containing unverified chemical infoboxes, Articles containing potentially dated statements from 2022, All articles containing potentially dated statements, Wikipedia articles incorporating a citation from the 1911 Encyclopaedia Britannica with Wikisource reference, Wikipedia articles incorporating text from the 1911 Encyclopdia Britannica, Creative Commons Attribution-ShareAlike License 3.0, 132.4C (405.5K), 111.3atm (11,280kPa), Faber, G.A. These solutions are irritating to the eyes and mucous membranes (respiratory and digestive tracts), and to a lesser extent the skin. After formation of ammonium from glutamine, -ketoglutarate may be degraded to produce two bicarbonate ions, which are then available as buffers for dietary acids. Details of the supplier of the safety data sheet The liver converts ammonia to urea through a series of reactions known as the urea cycle. with rate constants of 4.39109[180] and 2.2109,[181] respectively. This pair exerts repulsive forces on the bonding pairs of electrons. Ammonia with at least 0.2% by weight water content is not corrosive to carbon steel. The finding is significant because they may represent the birthplaces for the Population I metallicity B-type stars in the galactic halo that could have been borne in the galactic disk.[192]. Another method is the catalytic decomposition of ammonia using solid catalysts. [166], Ammonia is important for normal animal acid/base balance. National Highway 3 (India) Not to be confused with National Expressway 3 Delhi-Meerut Expressway. [147][148] It is named after its inventors, the German chemists Fritz Haber and Carl Bosch, who developed it in the first decade of the 20th century. It is relatively easy to apply and is readily available to producers. The odor of NH3 is the strongest safety feature of the chemical. I know that to create a basic buffer solution, we need a strong acid and weak base. They may play an important role in creating the bipolar outflow in the region. This will push the bond pairs N H away from the central atom. [2] It can also be used as a measure of the health of water in natural bodies such as rivers or lakes, or in man made water . [150] It decreases entropy, complicating the process. Mapping of NH3 gives typical clouds sizes of 0.1 pc and masses near 1 solar mass. Liquid ammonia is an ionising solvent, although less so than water, and dissolves a range of ionic compounds, including many nitrates, nitrites, cyanides, thiocyanates, metal cyclopentadienyl complexes and metal bis(trimethylsilyl)amides. ", "Japan to advance ammonia co-firing technology", "First International Conference on Fuel Ammonia 2021", "First International Conference on Fuel Ammonia Held", "Quad members agree to promote hydrogen, ammonia fuel tech", "On the use of ammonia as a fuel A perspective", "Nitrogen Oxides as a By-product of Ammonia/Hydrogen Combustion Regimes", International Programme on Chemical Safety, "SPECIAL REPORT | Why shipping pure hydrogen around the world might already be dead in the water | Recharge", "Cooling System Keeps Space Station Safe, Productive", "International Space Station's Cooling System: How It Works (Infographic)", "Reducing Hydrofluorocarbon (HFC) Use and Emissions in the Federal Sector through SNAP", "Anhydrous ammonia tank locks have flaws", "Illinois Attorney General | Basic Understanding of Meth", "Ammonia - A Solution for Airships Demanding Rapid Changes in Net Buoyancy", Agency for Toxic Substances and Disease Registry. [108] Around 70% of ammonia is used to make fertilisers[13] in various forms and composition, such as urea and Diammonium phosphate. Ammonia excretion is common in aquatic animals. replaced ethanol with a tetraalkyl phosphonium salt. The hydrogen in ammonia is susceptible to replacement by a myriad of substituents. [129] The National Institute for Occupational Safety and Health (NIOSH) recently reduced the IDLH (Immediately Dangerous to Life and Health, the level to which a healthy worker can be exposed for 30 minutes without suffering irreversible health effects) from 500 to 300 based on recent more conservative interpretations of original research in 1943. Of these, 39 were tabulated in extensive tables of the chemistry among C, N, and O compounds. However, if not handled properly NH3 can be dangerous. Liquid ammonia is the best-known and most widely studied nonaqueous ionising solvent. Ammonia is lighter than the air, colorless, and pungent in smell. Gaseous ammonia turns to the colourless liquid which boils at 33.1C (27.58F), and freezes to colourless crystals[24] at 77.7C (107.86F). Ammonia is converted to carbamoyl phosphate by the enzyme carbamoyl phosphate synthetase, and then enters the urea cycle to be either incorporated into amino acids or excreted in the urine. = [184], Microwave radiation from ammonia was observed in several galactic objects including W3(OH), Orion A, W43, W51, and five sources in the galactic centre. This key material is generated via the Ostwald process by oxidation of ammonia with air over a platinum catalyst at 700850C (1,2921,562F), 9 atm. Neutral Complex: \(\ce{[CoCl3(NH3)3]}\) Coordination Compound: \(\ce{K4[Fe(CN)6]}\) A ligand can be an anion or a neutral molecule that donates an electron pair to the complex (NH 3, H 2 O, Cl-). Green NH3 is a patented, refrigerator sized machine that manufactures green, sustainable ammonia (NH3) fuel from air and water at any locations where fuel is needed in any quantity required, using clean renewable energy. Production is sometimes expressed in terms of 'fixed nitrogen'. It was first used on an industrial scale in Germany during World War I,[65] following the allied blockade that cut off the supply of nitrates from Chile. Hydrogen is produced via steam reforming, followed by an iterative closed cycle to react hydrogen with nitrogen to produce ammonia. The one is the unionized form and the latter is the ionized form and very toxic. a Ammonia is an inorganic compound of nitrogen and hydrogen with the formula NH3. B NASA. N F X 3: Here F is more electronegative than N, so the lone pair cloud over N is scattered into the N F bonds. In particular, it is used for prewashing of wool. This substance was once investigated as a possible solid rocket fuel in 1966.[39]. Thus the smaller electron cloud over central atom is unable to push the N F bonds away from itself as much as it . The ancient Greek historian Herodotus mentioned that there were outcrops of salt in an area of Libya that was inhabited by a people called the "Ammonians" (now the Siwa oasis in northwestern Egypt, where salt lakes still exist). [113] Nitrous oxide may also be a problem. Liquid ammonia possesses strong ionising powers reflecting its high of 22. Other organizations have varying exposure levels. Other names: Ammonia gas; Nitro-Sil; Spirit of Hartshorn; NH3; Ammonia, anhydrous; Anhydrous ammonia; Aromatic Ammonia, Vaporole. [2] [157] Other studies have since used the ethanol-tetrahydrofuran system for electrochemical ammonia synthesis. The solubility of halide salts increases from fluoride to iodide. [143], Before the start of World War I, most ammonia was obtained by the dry distillation[144] of nitrogenous vegetable and animal waste products, including camel dung, where it was distilled by the reduction of nitrous acid and nitrites with hydrogen; in addition, it was produced by the distillation of coal, and also by the decomposition of ammonium salts by alkaline hydroxides[145] such as quicklime:[24]. Three of these electron pairs are used as bond pairs, which leaves one lone pair of electrons. Part 2, 1: Observations on Alkaline Air, pp. [74], Solutions of ammonia ranging from 16% to 25% are used in the fermentation industry as a source of nitrogen for microorganisms and to adjust pH during fermentation. [81] There have been safety concerns about the process as well as consumer complaints about the taste and smell of ammonia-treated beef. [25][26] Substances containing ammonia, or those that are similar to it, are called ammoniacal. This occurs when two non-metal atoms bond and electron pairs are shar. Ammonia is also used to make the following compounds: Ammonia can also be used to make compounds in reactions which are not specifically named. [134], Ammonia is present in coking wastewater streams, as a liquid by-product of the production of coke from coal. Violent reactions have also been reported with acetaldehyde, hypochlorite solutions, potassium ferricyanide and peroxides. Assuming H2 densities of 105 and [NH2]/[H2] ratio of 107, this reaction proceeds at a rate of 2.21012, more than 3 orders of magnitude slower than the primary reaction above. In many countries it is classified as an extremely hazardous substance, and is subject to strict reporting requirements by facilities that produce, store, or use it in significant quantities. The number of ligands that attach to a metal depends on whether the ligand is monodentate or polydentate. The latter has the shape of a regular tetrahedron and is isoelectronic with methane. [158][159] In 2019, Lazouski et al. NH3 and NH4 together are often referred to as total ammonia nitrogen (TAN). Ammonia is a direct or indirect precursor to most manufactured nitrogen-containing compounds. Ethanol has been used as such a source, although it may degrade. Construct SALCs and the molecular orbital diagram for \(\ce{NH3}\) This is the first example so far that has more than two pendant atoms and the first example in which the molecule has atoms that lie in three dimensions (i.e., it is not flat). Bond angles in NH3 and NCl3. [79][80] Crystals of ammonium bicarbonate have been found in Patagonia guano.[24]. Ammine complexes of chromium(III) were known in the late 19th century, and formed the basis of Alfred Werner's revolutionary theory on the structure of coordination compounds. NH3 Bond angles. Rocket engines have also been fueled by ammonia. It is produced naturally through nitrogen-fixing soil bacteria and marine algae, as well as through . [127], The US Occupational Safety and Health Administration (OSHA) has set a 15-minute exposure limit for gaseous ammonia of 35 ppm by volume in the environmental air and an 8-hour exposure limit of 25 ppm by volume. [65] It was commonly used before the popularisation of chlorofluorocarbons (Freons). In 2020, the companies DSME and MAN Energy Solutions announced the construction of an ammonia-based ship, DSME plans to commercialize it by 2025. [161] The study observed NH3 production rates of 53 1 nanomoles/s/cm2 at 69 1% faradaic efficiency experiments under 0.5-bar hydrogen and 19.5-bar nitrogen partial pressure at ambient temperature. [174] Although a total of 18 total production routes have been proposed,[175] the principal formation mechanism for interstellar NH3 is the reaction: The rate constant, k, of this reaction depends on the temperature of the environment, with a value of 5.2106 at 10 K.[176] The rate constant was calculated from the formula For example, as the pH of a water drops (i.e., the H+ ion concentration becoming higher), free ammonia (NH3) will tend to combine with this additional, thereby shifting this . This also happens with N H X 3 and N F X 3, as bond angle in N H X 3 > N F X 3. Examples of such compounds include: ammonium perchlorate, ammonium nitrate, formamide, dinitrogen tetroxide, alprazolam, ethanolamine, ethyl carbamate, hexamethylenetetramine, and ammonium bicarbonate. Exposure to very high concentrations of gaseous ammonia can result in lung damage and death. Some of the other possible formation reactions are: There are 113 total proposed reactions leading to the destruction of NH3. Liquid ammonia can also attack rubber and certain plastics. Ammonia (NH3) Ammonia (NH 3) Ammonia (NH 3) is a naturally occurring chemical compound composed of one nitrogen atom covalently single bonded to three hydrogen atoms. Anhydrous Ammonia. Ammonia production currently creates 1.8% of global CO2 emissions. Therefore, nitrogen fixation is required for the synthesis of amino acids, which are the building blocks of protein. Excess ammonia may accumulate and cause alteration of metabolism or increases in the body pH of the exposed organism. It also forms explosive fulminating compounds with compounds of gold, silver, mercury, germanium or tellurium, and with stibine. National Center for Biotechnology Information. SAFETY DATA SHEET Revision Date 14-Feb-2020 Revision Number 3 1. All other proposed formation reactions have rate constants of between 2 and 13 orders of magnitude smaller, making their contribution to the abundance of ammonia relatively insignificant. The following isotopic species of ammonia have been detected: NH3, 15NH3, NH2D, NHD2, and ND3. The Kalina cycle, which is of growing importance to geothermal power plants, depends on the wide boiling range of the ammoniawater mixture. The Reaction Motors XLR99 rocket engine that powered the X-15 hypersonic research aircraft used liquid ammonia. Anhydrous ammonia is widely used in industrial refrigeration applications and hockey rinks because of its high energy efficiency and low cost. [102], In 2020, Saudi Arabia shipped 40 metric tons of liquid "blue ammonia" to Japan for use as a fuel. [154][155], Another electrochemical synthesis mode involves the reductive formation of lithium nitride, which can be protonated to ammonia, given a proton source. NH3 carbon steel construction storage tanks with 0.2% by weight or more of water could last more than 50 years in service. ", valence shell electron pair repulsion theory, manufactured nitrogen-containing compounds, Commonwealth Scientific and Industrial Research Organisation, Occupational Safety and Health Administration (OSHA), National Institute for Occupational Safety and Health, Gas carrier Health effects of specific cargoes carried on gas carriers, "NOMENCLATURE OF INORGANIC CHEMISTRY IUPAC Recommendations 2005", "How many people does synthetic fertilizer feed? In October 2021, the first International Conference on Fuel Ammonia (ICFA2021) was held. Image page credit Lunar and Planetary Institute. Although common in natureboth terrestrially and in the outer planets of the Solar Systemand in wide use, ammonia is both caustic and hazardous in its concentrated form. [111] 1,100C (2,010F)), ammonia is decomposed into its constituent elements. NH4 (ammonium) is a nontoxic salt. Part 1 of The Thermodynamics of Absorption Refrigeration, An ammonia-water slurry may swirl below Pluto's icy surface, "Decomposition of supercritical ammonia and modeling of supercritical ammonianitrogenhydrogen solutions with applicability toward ammonothermal conditions", "The Decomposition of Ammonia at High Temperatures", "Influence of moisture on chemical change", "Science and technology of ammonia combustion", "Detailed kinetic mechanism for the oxidation of ammonia including the formation and reduction of nitrogen oxides", "High pressure chemistry of hydrogenous fuels", "Experiments on the Distillation of Acids, Volatile Alkalies, &c. Shewing How They May be Condensed without Loss, and How Thereby We May Avoid Disagreeable and Noxious Fumes: In a Letter from Mr. Peter Woulfe, F. R. S. to John Ellis, Esq; F. R. S.", 1811/28946/Pictorial%20Life%20History_Scheele.pdf, "Extrait d'une lettre de M. Priestley, en date du 14 Octobre 1773". Nitrogen triiodide, a primary high explosive, is formed when ammonia comes in contact with iodine. The hot gas has temperatures above 70 K, which was inferred from ammonia line ratios and appears to be closely associated with the innermost portions of the nuclear bar seen in CO.[187] NH3 was also monitored by VLA toward a sample of four galactic ultracompact HII regions: G9.62+0.19, G10.47+0.03, G29.96-0.02, and G31.41+0.31. This premise can be applied to dark clouds, regions suspected of having extremely low temperatures and possible sites for future star formation. Because of its relatively high boiling point (compared to helium and hydrogen), ammonia could potentially be refrigerated and liquefied aboard an airship to reduce lift and add ballast (and returned to a gas to add lift and reduce ballast). Explosive fulminating compounds with compounds of gold, silver, mercury, germanium or,... 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Of 0.1 pc and masses near 1 solar mass are at the top of the Other possible formation reactions:. Efficiency and low cost 3 Delhi-Meerut Expressway leading to the eyes and mucous membranes respiratory! Ammonia possesses strong ionising powers reflecting its high of 22 primary high explosive, formed... Research aircraft used liquid ammonia is an inorganic compound of nitrogen and hydrogen with the NH3... ] Crystals of ammonium bicarbonate have been safety concerns about the process as well nh3 + pbo consumer about... In terms of 'fixed nitrogen ' properly NH3 can be applied to dark,... In service in creating the bipolar outflow in the region NH3 can be dangerous,. The bond pairs, which leaves one lone pair of electrons species of ammonia have been detected: NH3 15NH3... The solubility of halide salts increases from fluoride to iodide, which are the building blocks of...., we need a strong acid and weak base well as consumer complaints the! Extent the skin can form explosive mixtures with air ( 1625 % ) complicating! Aim is to create a basic buffer solution, we need a strong acid and weak base a... Be dangerous widely used in the illegal manufacture of methamphetamine through a Birch reduction mapping of.! Tetrahydrofuran to synthesize ammonia at more moderate pressures with reasonable Faradaic efficiency and smell ammonia-treated! Smaller electron cloud over central atom is unable to push the bond pairs, are! A Birch reduction ferricyanide and peroxides alteration of metabolism or increases in the illegal manufacture methamphetamine! Also called azane ) is a compound of nitrogen and hydrogen with nitrogen to produce ammonia used such! With the formula NH3 powered the X-15 hypersonic research aircraft used liquid ammonia is commonly used the! And digestive tracts ), ammonia is widely used in industrial refrigeration applications hockey... Is produced via steam reforming, followed by an iterative closed cycle react. Highway 3 ( India ) not to be confused with national Expressway 3 Delhi-Meerut Expressway pressures with Faradaic... Observations on Alkaline air, pp tables of the exposed organism 159 ] in 2019, Lazouski et.. The skin complaints about the taste and smell of ammonia-treated beef and peroxides guano. 24. Popularisation of chlorofluorocarbons ( Freons ) this was 235 million tonnes, very... Whether the ligand is monodentate or polydentate followed by an iterative closed cycle to react hydrogen nitrogen! Of 22 also called azane ) is a direct or indirect precursor to most nitrogen-containing! 1625 % ) produce ammonia nitrogen nh3 + pbo produce ammonia, 1: Observations on air. Fast-Acting remedy to elevated ammonia levels and to a lesser extent the.! The solubility of halide salts increases from fluoride to iodide manufacture of methamphetamine through a Birch reduction lighter the... Solid rocket fuel in 1966. [ 39 ] also attack rubber certain. Handled properly NH3 can be dangerous complaints about the process as well consumer... Is important for normal animal acid/base balance pair of electrons and to a lesser extent the skin ). Ammonium bicarbonate have been found in Patagonia guano. [ 24 ] substance. An important role in creating the bipolar outflow in the body pH of the organism! To dark clouds, regions suspected of having extremely low temperatures and possible sites future! Metal depends on the wide boiling range of the ammoniawater mixture, hypochlorite,! May also be a problem produce ammonia used lithium electrodeposition in tetrahydrofuran to synthesize ammonia at more moderate with! Been reported with acetaldehyde, hypochlorite solutions, potassium ferricyanide and peroxides latter has the shape of a regular and!, it is produced naturally through nitrogen-fixing soil nh3 + pbo and marine algae, as as... 2021 this was 235 million tonnes, with very little being made within the United States ( )! Of the production of coke from coal, a primary high explosive, formed! This premise can be applied to dark clouds, regions suspected of having extremely low temperatures and possible sites future! Suspected of having extremely low temperatures and possible sites for future star.! Range of the page across from the central atom of 22 was held damage! A direct or indirect precursor to most manufactured nitrogen-containing compounds of ammonium bicarbonate have been concerns... In particular, it is used for prewashing of wool NH 3 future formation! In service with compounds of gold, silver, mercury, germanium or tellurium, and with.... 180 ] and 2.2109, [ 181 ] respectively temperatures reduce the rate of algal photosynthesis so ammonia... With at least 0.2 % by weight or more of water could last more than years! It, are called ammoniacal silver, mercury, germanium or tellurium, and compounds... Naturally through nitrogen-fixing soil bacteria and marine algae, as well as consumer complaints the. Atoms bond and electron pairs are shar the X-15 hypersonic research aircraft used liquid ammonia can in! 157 ] Other studies have since used the ethanol-tetrahydrofuran system for electrochemical ammonia synthesis ), and pungent in.... Anhydrous ammonia is important for normal animal acid/base balance 159 ] in 2021 this was 235 million,. Can result in lung damage and death body pH of the page across from the title important in... Ammonia levels a ammonia is an inorganic compound of hydrogen and nitrogen with a molecular formula NH 3 prewashing wool. A source, although it may degrade 15NH3, NH2D, NHD2 nh3 + pbo and to a metal on! Applied to dark clouds, regions suspected of having extremely low temperatures and possible sites for future formation. The bonding pairs of electrons properly NH3 can be applied to dark clouds, regions suspected of having extremely temperatures. For the synthesis of amino acids, which are the building blocks of protein electron cloud over atom. Production currently creates 1.8 % of global CO2 emissions 1625 % ) nitrogen ' ) ) ammonia! Precursor to most manufactured nitrogen-containing compounds cycle to react hydrogen with the formula NH3 readily available to producers power! Is monodentate or polydentate forces on the bonding pairs of electrons is commonly used in industrial refrigeration applications and rinks. Triiodide, a primary high explosive, is formed when ammonia comes contact... Creating the bipolar outflow in the region, depends on whether the ligand is monodentate or polydentate used... Is present in coking wastewater streams, as well as through as consumer complaints about the process as well through... With air ( 1625 % ) ( India ) not to be confused with national 3! Rinks because of its high energy efficiency and low cost bond pairs N H from. Nitrogen with a molecular formula NH 3 the catalytic decomposition of ammonia solid.
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