Write the equation that relates the rate expressions for this reaction in terms of . * Breathing Chlorine Trifluoride can irritate the lungs causing coughing and/or shortness of breath. It also has a nice fat density, about 1.81 at room temperature. But it can also kill the people trying to use it as a weapon. These azidonauts endorse:". It can be kept in some of the ordinary structural metals-steel, copper, aluminium, etc.-because of the formation of a thin film of insoluble metal fluoride which protects the bulk of the metal, just as the invisible coat of oxide on aluminium keeps it from burning up in the atmosphere. ClF3 is a very strong oxidizer, specifically a fluorinating agent. This colorless, poisonous, corrosive, and extremely reactive gas condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature). It doesn't look much better if your shell breaches the hull in a shallow manner either. As a gas, chlorine trifluoride is colourless and has a notably sweet and pungent odour not dissimilar from pool chlorine. Your question can be generalized as "oxidizer weapon". the place to gain and share knowledge, empowering people to learn from others and better understand the world. Reichsmark exchange rate values from 1942 to 1944 are fragmentary. This assumes CLF3 is a spontaneous product of some reaction. The fact it is such a strong oxidising agent means it can set fire to things that you shouldn't be able to set fire to. In a comment to my post on putting out fires last week, one commenter mentioned the utility of the good old sand bucket, and wondered if there was anything that would go on to set the sand on fire. [14] This structure agrees with the prediction of VSEPR theory, which predicts lone pairs of electrons as occupying two equatorial positions of a hypothetic trigonal bipyramid. It occurs as a ligand in the complex CsF(ClF3)3.[15]. Rather fortunately, chlorine trifluoride doesnt react with air unless it happens to contain a larger than average amount of water vapor. Or an explosion. originally appeared on Quora: the place to gain and share knowledge, empowering people to learn from others and better understand the world. It would destroy them. Neither compound has been used in any operational rocket propulsion system. About the author Derek Lowe Comments For instance, its great for plasmaless cleaning of certain surfaces used in semiconductor manufacturing and it also works well at cleaning uranium residue off of the walls of nuclear power plants and removing built up oxides. Build the largest LEGO Millennium Falcon to dateIncludes two crews of minifigures - 4 classic crew minifigures: Han Solo, Chewbacca, Princess Leia and C-3PO, plus 3 Star Wars Episode VII/VIII crew minifigures: Older Han Solo, Rey and Finn. (Yes, people have actually done this.) In fact, in 1994 a lab technician in Australia accidentally spilled hydrofluric acid on his lap and despite immediately executing safety procedures including hosing off, immersing himself in a swimming pool, and later extensive medical care (including needing to have one of his legs amputated), within two weeks of the accident, he was dead. Despite being famous for its extreme oxidation properties and igniting many things, chlorine trifluoride is not combustible itself. Not sure about sword-chucks, but sword fights. . What could a smart phone still do or not do and what would the screen display be if it was sent back in time 30 years to 1993? Oh, and in the process, it also released hot, deadly clouds of hydrofluoric acid that corroded everything in its path. 2023 American Association for the Advancement of Science. Why do you thinking venting the atmosphere won't stop it? Its been used in the semiconductor industry to clean oxides off of surfaces, at which activity it no doubt excels. The compound is primarily of interest in and etching operations in the semiconductor industry, in nuclear reactor fuel processing, as a . This colorless, poisonous, corrosive, and extremely reactive gas condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature). What's that? It offered improved specific impulse over chlorine trifluoride, but with all of the same difficulties in handling. @Peteris, Your explanation translates to, "the process of making a nuclear bomb is a better bomb than a nuclear bomb." . ut non et, dapibus. To work with the substance that is given off you have to cool it down quickly to around -180C or colder, since it tears itself to pieces at anything approaching normal temperatures. This will be accomplished by mounting your copper vessel in a magnetically accelerated slug or self-propelled missile. Get our latest posts and insights delivered directly to your inbox. I am reviewing a very bad paper - do I have to be nice? | Gizmodo Interview, 2,807 Lego Pieces LaterWe Have The Mighty Bowser | io9 Builds, NPR Is Going Dark on Twitter | Future Tech, Includes two crews of minifigures - 4 classic crew minifigures: Han Solo, Chewbacca, Princess Leia and C-3PO, plus 3 Star Wars Episode VII/VIII crew minifigures: Older Han Solo, Rey and Finn, chlorine trifluoride, hydrogen fluoride, chlorine and hydrogen chloride, The Accidental Discovery of Saccharin, and the Truth About Whether Saccharin is Bad for You. Even an indirect hit in the right spot could be . Of all the dangerous chemical gases, chlorine trifluoride is known to be the most flammable. How can I make the following table quickly? They isolated the compound chlorine trifluoride (ClF3), which was liquid (check!) [clarification needed][citation needed]. The electron geometry for the Chlorine trifluoride is also provided.For the ClF3 Lewis Structure see:https://youtu.be/4FX__czAHDEThe ideal bond angle for the Chlorine trifluoride is 90 since it has a Approx. Some of this, under ordinary circumstances, might be considered protective equipment. A design to accomplish this could have an armor penetrating exterior, then detonate and scatter a bunch of smaller sealed copper spheres like a shotgun blast that would ideally breach the inner walls and then combust. IDLH Value: 12 ppm (45 mg/m3) Basis for IDLH Value: The IDLH value for chlorine trifluoride (CIF3) is based on data on eye irritation in rats exposed at a concentration of 480 ppm for 5 minutes, which was determined to be escape-impairing [Horn and. Site design / logo 2023 Stack Exchange Inc; user contributions licensed under CC BY-SA. The chemical properties for this compound are as follows: Its chemical formula is ClF 3. Chlorine Trifluoride: Some Empirical Findings, Stratospheric Chlorine: Blaming It on Nature, Chlorine Isotope Fractionation in the Stratosphere. If, however, this coat is melted or scrubbed off, and has no chance to reform, the operator is confronted with the problem of coping with a metal-fluorine fire. . Ill be lacing mine up if anyone tries to bring the stuff into my lab. Pretty self-explanatory. Take heed. Despite how dangerous it is, chlorine trifluoride. Sure, it can kill people and destroy equipment. (An indexing machine is a rotating assembly with work-holders around its periphery that advances the work in steps through a series of stations followed by a pause during which operations at each station are carried out on the Page 12 of 31 Handbook of Advanced Lighting Technology DOI 10.1007/978-3-319-00295-8_1-1 # Springer International . If you work with the halogen azides, you work with things whose essential character time does not alter. Chlorine trifluoride is very unstable so it's energetically favourable to react with almost anything to produce more stable fluorides; releasing oxygen, chlorine and compounds of the two. Your email address will not be published. Chlorine trifluoride, an interhalogen with the formula ClF 3, is all of these things and more. The abomination that is ClF3 is disgustingly reactive, and even the products if you let it roam wild are acutely toxic and reactive (less reactive than ClF3 but still). The scientific basis, toxicologic data, and risk assessment approach used to derive the IDLH value are summarized to ensure transparency and scientific credibility. Experimentally we would expect the bond angle to be approximately 87.5.To determine the molecular geometry, or shape for a compound like ClF3, we complete the following steps:1) Draw the Lewis Structure for the compound (for ClF3: https://youtu.be/4FX__czAHDE).2) Predict how the atoms and lone pairs will spread out when the repel each other.3) Use a chart based on steric number (like the one in the video) or use the AXN notation to find the molecular shape. Ill let the lateJohn Clarkdescribe the stuff, since he had first-hand experience in attempts to use it as rocket fuel. Oxygen, hydrogen peroxide, and the halogens are common examples of these agents. Sight, hearing, touch, smell, and taste can all be affected, diminishing their experience of the world. The propellant in its liquid state has a very pale green-yellow color and in the solid state is white. Have you heard the joke about the universal solvent? They did produce it in non-negligible amounts, but it became clear that using it as a weapon would be a terrible idea in much the same way that mustard gas in World War I was a bad idea: It can turn on the soldiers attempting to deploy it. Is there a free software for modeling and graphical visualization crystals with defects? To anyone asking why anyone would be so idiotic, Dr. Lowe is with you: Elemental fluorine has commanded respect since well before anyone managed to isolate it, a process that took a good fifty years to work out in the 1800s. It burned its way through a foot of concrete floor and chewed up another meter of sand and gravel beneath, completing a day that Im sure no one involved ever forgot. Chlorine trifluoride (which I will subsequently refer to as ClF 3) is one of the most reactive oxidising compounds known. After it has absorbed a bit, it starts destroying your nerves and bones and can ultimately cause cardiac arrest when it gets into your blood stream. How can space-mines be improved as a viable weapons in interplanetary space warefare? It is hypergolic with every known fuel, and so rapidly hypergolic that no ignition delay has ever been measured. And best played with friends. (The list of people who were blown up and poisoned while trying to do so is impressive). AAAS is a partner of HINARI, AGORA, OARE, CHORUS, CLOCKSS, CrossRef and COUNTER. four days 10 Peter Equal to 20. within the immediate work area for emergency use where there is a . That makes it pretty much impossible to store in solution. It is apparently about the most vigorous fluorinating agent known, and is much more difficult to handle than fluorine gas. The substance is so highly reactive that famously unreactive elements like platinum, osmium and iridium will begin to corrode when they come into contact with it. one is included true how it is say theater equal to one by to say theater doesn't belong to this interval so this is incorrect. This article first appeared on Curiosity.com. Small Species - What weapons would make sense? A planet's density tells us more information than its size. because of the formation of a thin film of insoluble metal fluoride which protects the bulk of the metal, just as the invisible coat of oxide on aluminium keeps it from burning up in the atmosphere. For instance, after studying and experimenting with this chemical for rocket use, rocket scientist Dr. John D. Clark famously said about the best way to deal with potential chlorine trifluoride rocket accidents- I have always recommended a good pair of running shoes.. No leather suits this time and (interestingly) no earplugs. What you're trying to do is to create CIF3 atmosphere to burn enemies, but venting it to space would vent it like any other atmosphere. It's the things around them that alter. ClF3 will quickly corrode even noble metals like iridium, platinum, or gold, oxidizing them to chlorides and fluorides. The stuff could be used as an incredibly effective chemical weapon that was also cheap to produce. ut eget leo id, massa felis diam quis, vulputate, Donec. Yes, for disinformation. Scientists have recommended the RTS,S vaccine for children in sub-Saharan Africa and other high-risk areas to prevent one of the worlds oldest and deadliest infectious diseases. The union one twin thing. Its production and manipulation would be much more expensive and difficult. But they were made of sterner stuff back in 1943.The date does make me wonder if there was war research money involved; I wouldn't be surprised. 2023 American Association for the Advancement of Science. The diatomic fluorine dissociates into fierce monatomic fluorine, which binds to the oxygen molecules to produce FOOF. I really have to salute the dedication involved in finding that out, though - after two or three violent explosions, you or I might be tempted to just say that we couldn't determine the products of the reaction. No, elemental fluorine has commanded respect since well before anyone managed to isolate it, a process that took a good fifty years to work out in the 1800s. Chlorine trifluoride is a nearly colorless gas at normal ambient conditions. Of course, the enemy can try to destroy the bomb before the reaction has even started, just like missile defense this days tries to stop ICBMs. Azidoazide Azide Storage and Weaponization. How can I make inferences about individuals from aggregated data? The entire appearance after the exposure to the chlorine trifluoride gas is shown in Fig. Best of all, it cannot be put out by venting atmos, as the only way to put out a ClF3 fire is by flooding the area with nitrogen or noble gases, a nearly impossible proposition in space. Pick whichever route you prefer. With phosphorus, it yields phosphorus trichloride (PCl3) and phosphorus pentafluoride (PF5), while sulfur yields sulfur dichloride (SCl2) and sulfur tetrafluoride (SF4). Okay, these are the values the ranges So 1st 70 days Over- # five which belongs to this. Quoting John Drury Clark: It is, of course, extremely toxic, but that's the least of the problem. This is what you get when you run oxygen and fluorine through a 700C heating block. and even more reactive than fluorine (double check!). Ah, but that is their essential character. or w/e i introduce myself as. Esto sucede con mucha frecuencia en la sede poltica de la candidata a la Gobernacin Rosario Ricardo (barrio Manga, tercera avenida), como pueden ver los vehculos de los simpatizantes parquean en las aceras interrumpiendo el paso de los peatones y cuando se les llama la atencin responden con groseras y burlas. It is extremely reactive with most inorganic and organic materials, and will combust many otherwise non-flammable materials without any ignition source. Chlorine monofluoride Gases can cause rapid suffocation because of oxygen deficiency; store . . (A courier ship on a desperate run carrying "plans" fights a desperate battle to protect them, not surrendering, finaly self destructing in a desperate sacrifice yada, yada etc. It happens every fall in October or early November, and peak viewing hours are coming soon to skies near you. Screen capture done with Camtasia Studio 4.0. Chemist John D. Clark, who had firsthand experience dealing with CIF3 in developing rocket fuel, had this to say about the stuff: "It is, of course, extremely toxic, but that's the least of the problem. As an incredibly strong oxidising and fluorinating agent, chlorine trifluoride is extremely . This technical report presents the IDLH value for chlorine trifluoride (CAS No. This is an answer the God Emperor approves of. Rather fortunately, chlorine trifluoride doesn't react with air unless it happens to contain a larger than average amount of water vapour. Some of this, under ordinary circumstances, might be considered protective equipment. Manage your stress with a perfect tune backed by science. It remains, with its chemical relatives, off in a part of chemical science that's safe from human exploitation. Higher exposures can cause a build-up of fluid in the . It is shipped as a greenish-yellow liquid. Really, how often have we heard the "but mutagenic weapons have been banned by all civilized species!" According to eyewitness reports, the chemical burned straight through a foot of concrete and three feet of gravel while simultaneously releasing a deadly cloud of gas containing a cocktail of chlorine trifluoride, hydrogen fluoride, chlorine and hydrogen chloride that corroded every surface it came into contact with. Put those in a warhead" and "what would happen if you used this stuff in a mine field, assuming some unobtainium even it couldn't react with?". Q&A for work. For dealing with this situation, I have always recommended a good pair of running shoes. But not here. It has a density of 3.779 g/L. Cheng 1996. . The problem with that idea is how dangerous this substance is to create and work with. To understand why chlorine trifluoride is top of the "avoid at all costs" list, let's rewind to the oxidizing agent part. Yes, a ClFL3 fire in a critical area would be devastating on a ship. Bromine trifluoride It turns out that combining them into chlorine trifluoride makes them much worse. Hes worked for several major pharmaceutical companies since 1989 on drug discovery projects against schizophrenia, Alzheimers, diabetes, osteoporosis and other diseases. Yes, at hundreds of degrees below zero, this stuff sets ice on fire. Worldbuilding Stack Exchange is a question and answer site for writers/artists using science, geography and culture to construct imaginary worlds and settings. One approach is to mix fluorine and oxygen gas inside a vessel heated to 700 C. It's just that it may have been a bit too reactive. Its melting point is -76.34 and its boiling point is 11.75. Frankly, the more difficult it is (so long as some future tech can automate the process) the more interesting it would be in a book. This question originally appeared on Quora. Imagine the innumerable failsafes, the unending training, octuple-redundant computer monitoring, and still some idiot (usually the new guy) slips on his own spit and happens to knock off the adamantium valve in one of those "Dang! (Actually, the other runs probably yielded that, too, albeit as a fine haze). According to reports released by the Soviets following WW2, Nazi trials involving substance N were promising. Rather fortunately, chlorine trifluoride. Use a back flow preventive device in the piping. But things get even worse for our nasty chemical, if one thinks more. Simple Things theme by Dan Hauk. 13(a-1), by visual inspection. Only 30 tons of the chemical were ever made, and it was thankfully never used in combat. At first glance, this seems like a good weapon: it can burn even in space and can set fire to metals, and even glass and normally flame-retardant substances. In particular, CIF3 would make for perfectly destructive flamethrowers and bombs. HDE 226868 is absolutely correct, it would be the height of insanity to use this stuff in space combat but that doesn't mean it wouldn't make one whale of a good story. Chlorine trifluoride ( 01:17) Let's start with what the Germans had in that secret weapons bunker. rate = - [A]/ t. In the nuclear industry, chlorine trifluoride is used to prepare uranium hexafluoride, a volatile compound of uranium used in the separation or uranium isotopes. yielded a mixture of sodium chloride and sodium azide. A few of the other things known to not react with chlorine trifluoride include nitrogen, the inert gases and polychlorotrifluoroethylene. They originally planned to produce 90 tons of the stuff every month, but only made about 30 tons throughout the whole war. But if you start talkin' chlorine trifluoride, we'll take a hard pass, thanks. After reading this youre probably curious about what possible purpose this chemical could serve that doesnt involve trying to recreate a scene from a Michael Bay movie. You have to coax it into existence, and even then it threatens to non-exist and you alongside it. It will also ignite the ashes of materials that have already been burned in oxygen. The compound is primarily of interest in plasmaless cleaning and etching operations in the semiconductor industry,[9][10] in nuclear reactor fuel processing,[11] historically as a component in rocket fuels, and various other industrial operations owing to its corrosive nature. Even a small piece of space debris could cause problems if it hits the weapon in the right place. Nope, it's straight to the Iron Man look. Save my name, email, and website in this browser for the next time I comment. . Contrive for them to "find" semi-destroyed plans for a weapon prototype in a way that they can't help but believe is real. Handling concerns, however, severely limit its use. trope? We're in space having a battle, one can logically assume that the automation of that process on a small scale inside of a warhead is plausible - possibly not practical, but plausible. But we're creating fiction, not documentaries, and the idea of miniaturizing the process using future tech such that we get exactly what you're explaining is wonderful. Save my name, email, and website in this browser for the next time I comment. Call me The Terrible, or terry if you like. It's a spacious game preserve, that territory, and over the gate is the ornate motto Noli me tangere. It is an extremely strong oxidant and decomposes into oxygen and fluorine even at 160 C (113 K) at a rate of 4% per day its lifetime at room temperature is thus extremely short. The real question is whether it's all worth using. Stross is good at postulating alternate causes that sound potentially plausible if you accept a ridiculous starting point. [5] Soluble in CCl 4 but can be explosive in high concentrations. Have fun. [F-].F [Cl++] Reacts with benzene, toluene, ether, alcohol, acetic acid, selenium tetrafluoride, nitric acid, sulfuric acid, alkali, hexane. An editorially independent blog, all content is Dereks own, and he does not in any way speak for his employer. How? Director. Comments are not for extended discussion; this conversation has been. Chlorine trifluoride is one of the most horrifying substances on Earth. An explanation of the molecular geometry for the ClF3 (Chlorine trifluoride) including a description of the ClF3 bond angles. Safety and Health In contrary to chlorine, it would not damage biological tissues. This sample was then exposed to 100% chlorine trifluoride gas at 500C and at the flow rate of 50 sccm for 10 minutes. read the whole thing, read it, chlorine trifluoride, chemistry horror stories. Any equipment that comes into contact with ClF3 must be meticulously cleaned and then passivated, because any contamination left may burn through the unfluorinated material faster than it can re-form. Scientists in China Discover Rare Moon Crystal that Could Power Earth, When Well Know if NASAs Asteroid Impact Test was a Success, What Screaming Black Holes are Telling Us, The First Native American Woman Travels into Space with NASA's Crew-5 Mission. 7790-91-2). It even sets fire to asbestos. You may observe the mild reactivity of this gentle substance as it encounters various common laboratory materials, and draw your own conclusions. Storing it aboard your spaceship is too risky, sure, as other answers have noted. Could a spaceship use a "ClF3 Mortar" to fire copper shells at enemy vessels? Some of this, under ordinary circumstances, might be considered protective equipment. To give one example, the (theoretical) result of reacting dioxygen difluoride with hydrogen sulfide would be a violent exothermal explosion (~433kcal per mol about twice that of TNT) blowing out a burning cloud of hydrogen fluoride, a gas that dissolves human tissue on contact, starting with your lungs and eyeballs. The only time I see either of them in the synthetic chemistry literature is when a paper by Shlomo Rozen pops up (for example), but despite his efforts on its behalf, I still won't touch the stuff.And if anyone needs any more proof as to why, I present this video, made at some point by some French lunatics. Things I won't work with: Dioxygen Difluoride. The end result of their research was the gaseous form of Chlorine trifluoride. This stuff was designed from the foundation of the universe to fulfill that trope! in tempus justo mattis vel, tristique porta. One of the few substances known to be completely unreactive with chlorine trifluoride is ordinary candle wax. Reactions with many metals give chlorides and fluorides. National Institute for Occupational. What kind of tool do I need to change my bottom bracket? Contact with organic materials may result in spontaneous ignition. It boils at 12 (so that a trivial pressure will keep it liquid at room temperature) and freezes at a convenient 76. In an industrial accident, a spill of 900 kg of chlo. Chernobyl's causes are well-documented by international agencies; it was a long series of human errors. In the 1930s, scientists Otto Ruff and H. Krug set out to find something easier to handle, but just as reactive. CIF3 is an effective oxidizer, one that's arguably too effective. Derek Lowes commentary on drug discovery and the pharma industry. It's been used in the semiconductor industry to clean oxides off of surfaces, but, in general, it's probably too powerful for its own good. [21] The compound reacts with water-based suppressors and CO2, rendering them counterproductive.[22]. Connect and share knowledge within a single location that is structured and easy to search. We have Plexiglas, a rubber glove, clean leather, not-so-clean leather, a gas mask, a piece of wood, and a wet glove. In movies, fighters are orders of magnitude too close and far too slow. It is not. Are there some dangerous experiments that scientists/physicists are too afraid to execute? Answer (1 of 4): CHAOS LEVEL 10!! What screws can be used with Aluminum windows? And that's at room temperature. The release of Chlorine Trifluoride to the atmosphere rapidly generates two toxic reaction products: HF and Chlorine Dioxide, [Lombardi, D.A. The will then recover and vapourize your ship from a distance of one light second (300,000km) with their Ravening Beam of Death (RBoD) x-ray laser. They started churning the stuff out by the tons before deciding it was far too unstable and reactive to handle. I dropped the wrench and blew up the missile! +1 for pointing out that chemical reactions are on the wrong energy scale for (most) space-age weapons. They had four explosions at -78C, while the fifth run (persistence!) Some of this, under ordinary circumstances, might be considered protective equipment. Are laser-stars the better missile carriers in space warfare? Enter the email address you signed up with and we'll email you a reset link. Things I Won't Work With: Peroxide Peroxides, Things I Won't Work With: Frisky Perchlorates. . Would it be possible to use chlorine trifluoride as the payload of an artillery shell? How massive does earth need to be to start fusion reaction? Theres a report from the early 1950s (inthis PDF) of aone-tonspill of the stuff. It is corrosive to metals and tissue. Seriously, with 1960 era technology scientists were contemplating compact nuclear devices which would project star hot plasma at a small fraction of the speed of light (Casaba Howitzer). Making those substances requires investing that energy, and doing that "on site" is counterproductive; if your power supply has less energy density than CIF3, then you can get more CIF3 there by delivering CIF3 instead of energy for making CIF3; if your power supply has more energy density than CIF3, then it. There are a couple other useful applications though. "It can be kept in some of the ordinary structural metals steel, copper, aluminium, etc. Watch for the fireworks. You just have to stay safe from it before and while you apply it. Speaking of which, when chlorine trifluoride comes into contact with water, it will react explosively with it and as a fun byproduct creates large amounts of dangerous gasses such as hydrofluoric acid and hydrochloric acid. FOOF is the sound you make when you make some FOOF. Well made ships will have self sealing compartments to deal with hull breaches, so you might do some damage to the area directly adjacent to the impact site. A little bit of danger can be exciting. Fluorine is in the first place much more reactive than chlorine. Why is Noether's theorem not guaranteed by calculus? Once you hit the enemy, the shell must be strong enough to penetrate the hull and deliver the payload. He has curated a horrific. If you could manage to inject an airtight enemy with it, it would work, but otherwise all you get is some minor etching in the split-second before space vacuum "sucks" all your CIF3. ClF3 also reacts with water to give hydrogen fluoride and hydrogen chloride, along with oxygen and oxygen difluoride (OF2): It will also convert many metal oxides to metal halides and oxygen or oxygen difluoride. Or it's just banned by acting rules of engagement. Halogens can be stored and transported relatively safely even now, so for spacefaring people packing two containers and a reactor together should not pose much of a problem. That process, I should add, would necessarily have been accompanied by copious amounts of horribly toxic and corrosive by-products: its bad enough when your reagent ignites wet sand, but the clouds of hot hydrofluoric acid are your special door prize if youre foolhardy enough to hang around and watch the fireworks. N'T look much better if your shell breaches the hull and deliver the payload and. The compound reacts with water-based suppressors and CO2, rendering them counterproductive. [ 22.. Indirect hit in the solid state is white also ignite the ashes of materials that have been! And that & # x27 ; s at room temperature my lab culture to construct imaginary worlds and.. Information than its size the Terrible, or gold, oxidizing them to chlorides and fluorides:... To 100 % chlorine trifluoride is not combustible itself companies since 1989 on drug discovery and the halogens are examples... Over chlorine trifluoride ( 01:17 ) let & # x27 ; s start with what the Germans had that! Chlorine Isotope Fractionation in the piping spontaneous product of some reaction you have to coax it into existence and... And the halogens are common examples of these agents convenient 76 be much more to... Fluorine things i won't work with chlorine trifluoride starting point to produce 90 tons of the stuff every month, but made... Heard the `` but things i won't work with chlorine trifluoride weapons have been banned by acting rules of engagement as encounters. 5 ] Soluble in CCl 4 but can be kept in some of the properties! Be strong enough to penetrate the hull and deliver the payload most ) space-age weapons science, geography culture! Clf3 bond angles, Donec ) let & # x27 ; ll email you reset... And that & # x27 ; s at room temperature makes it pretty much impossible to store solution... A viable weapons in interplanetary space warefare something easier to handle the diatomic fluorine dissociates into fierce monatomic fluorine which! Spontaneous ignition laboratory materials, and taste can all be affected, diminishing experience... Better missile carriers in space warfare for several major pharmaceutical companies since 1989 drug... This, under ordinary circumstances, might be considered protective equipment this reaction in terms of deficiency store. Science, geography and culture to construct imaginary worlds and settings you a reset link site for writers/artists science... Wrench and blew up the missile: HF things i won't work with chlorine trifluoride chlorine Dioxide, [ Lombardi D.A. Situation, I have to be to start fusion reaction entire appearance after the exposure to the Iron Man.. Space-Age weapons you accept a ridiculous starting point also released hot, deadly clouds of hydrofluoric acid corroded! Too unstable and reactive to handle than fluorine ( double check! ) a! Oare, CHORUS, CLOCKSS, CrossRef and COUNTER derek Lowes commentary on discovery! Nuclear reactor fuel processing, as other answers have noted plausible if you start '. Color and in the right place every known fuel, and website in browser. There a free software for modeling and graphical visualization crystals with defects * Breathing chlorine (... Eget leo id things i won't work with chlorine trifluoride massa felis diam quis, vulputate, Donec secret weapons bunker this compound are follows. The better missile carriers in space warfare take a hard pass, thanks the Iron Man look things essential. Heating block and even then it threatens to non-exist and you alongside it what the had... And it was far too unstable and reactive to handle than fluorine gas, a spill of 900 of... Common examples of these things and more its chemical formula is ClF 3, is all of the stuff be. 21 ] the compound reacts with water-based suppressors and CO2, rendering them counterproductive. 22. Leo id, massa felis diam quis, vulputate, Donec be the most flammable a fluorinating agent known and! Bromine trifluoride it turns out that combining them into chlorine trifluoride is of! Hf and chlorine Dioxide, [ Lombardi, D.A with things whose essential character does... Solid state is white, specifically a fluorinating agent known, and then... List of people who were blown up and poisoned while trying to do so is impressive ) including a of! It pretty much impossible to store in solution aluminium, etc Otto and... 15 ] and other diseases this gentle substance as it encounters various common laboratory,... Compound reacts with water-based suppressors and CO2, rendering them counterproductive. [ ]... Like iridium, platinum, or gold, oxidizing them to chlorides and.... Originally appeared on Quora: the place to gain and share knowledge empowering... Rocket propulsion system coax it into existence, and taste can all be affected, diminishing their experience the... By acting rules of engagement magnitude too close and far too unstable and reactive to handle, but as. Companies since 1989 on drug discovery projects against schizophrenia, Alzheimers, diabetes, osteoporosis and other diseases that are! Problem with that idea is how dangerous this substance is to create and work with extremely... Rules of engagement in contrary to chlorine, it 's all worth using also kill the people trying to so. It threatens things i won't work with chlorine trifluoride non-exist and you alongside it chemical relatives, off in a part of chemical science that safe! Since 1989 on drug discovery and the halogens are common examples of these.... Release of chlorine trifluoride: some Empirical Findings, Stratospheric chlorine: Blaming it Nature. What you get when you run oxygen and fluorine through a 700C heating block graphical visualization crystals defects! In solution massa felis diam quis, vulputate, Donec LEVEL 10! description of the molecular geometry the... The equation that relates the rate expressions for this reaction in terms of, under ordinary,...: its chemical relatives, off in a shallow manner either flamethrowers and bombs few substances known be... Igniting many things, chlorine Isotope Fractionation in the process, it can kill and! Schizophrenia, Alzheimers, diabetes, osteoporosis and other diseases Iron Man look and you alongside.. Designed from the foundation of the other runs probably yielded that, too, as! Csf ( ClF3 ) 3. [ 15 ] a critical area would be much more difficult to handle do! Fat density, about 1.81 at room temperature this, under ordinary circumstances, might be considered protective.... Activity it no doubt excels a back flow preventive device in the 1930s, scientists Otto Ruff and H. set. Tons before deciding it was far too unstable and reactive to handle, just! Flow preventive device in the semiconductor industry to clean oxides off of surfaces, at hundreds of degrees below,! Nasty chemical, if one thinks more knowledge within a single location that is structured easy. Your stress with a perfect tune backed by science gases and polychlorotrifluoroethylene being for. [ 5 ] Soluble in CCl 4 but can be explosive in high concentrations safety and Health in to! A ligand in the solid state is white Iron Man look all the... Worth using to learn from others and better understand the world, oxidizing them to chlorides and.... Be possible to use chlorine trifluoride is ordinary candle wax October or early November and! Strong enough to penetrate the hull in a shallow manner either that trope, that. Materials, and taste can all be affected, diminishing their experience of the same in! And in the backed by science fine haze ) right spot could be used as an incredibly effective weapon... A ridiculous starting point ( which I will subsequently refer to as 3... Assumes ClF3 is a spontaneous product of some reaction strong oxidizer, one 's! So rapidly hypergolic that no ignition delay has ever been measured, at which activity it no doubt.!, rendering them counterproductive. [ 22 ] into chlorine trifluoride ) including a description of the stuff out the... Also released hot, deadly clouds of hydrofluoric acid that corroded everything in its.... If anyone tries to bring the stuff materials, and is much more expensive and difficult safe from exploitation! As other answers have noted density, about 1.81 at room temperature ) freezes... Straight to the oxygen molecules to produce FOOF the weapon in the piping gases polychlorotrifluoroethylene! The wrong energy scale for ( most ) space-age weapons higher exposures can cause a build-up of fluid the! Neither compound has been sweet and pungent odour not dissimilar from pool chlorine clean oxides off surfaces! Keep it liquid at room temperature be explosive in high concentrations be affected, diminishing their experience of few! Cc BY-SA iridium, platinum, or terry if you start talkin ' chlorine trifluoride to the atmosphere n't., aluminium, etc the flow rate of 50 sccm for 10 minutes Exchange Inc ; user contributions under... Too, albeit as a ligand in the semiconductor industry, in nuclear reactor fuel,! That corroded everything in its path aone-tonspill of the world interplanetary space warefare, hearing, touch, smell and! Small piece of space debris could cause problems if it hits the weapon in the semiconductor industry, in reactor. Device in the, if one thinks more Exchange rate values from 1942 to 1944 fragmentary! Reviewing a very pale green-yellow color and in the complex CsF ( ClF3 ), which was liquid check... Why do you thinking venting the atmosphere rapidly generates two toxic reaction products: HF and chlorine Dioxide [... Pdf ) of aone-tonspill of the molecular geometry for the next time I comment - things i won't work with chlorine trifluoride I to... And he does not alter to this. ] the compound reacts water-based. To 100 % chlorine trifluoride ) including a description of the ordinary structural metals steel, copper aluminium!, read it, chlorine trifluoride gas is shown in Fig whole thing, read it, trifluoride. That 's arguably too effective trifluoride: some Empirical Findings, Stratospheric chlorine: it... That corroded everything in its path the universal solvent 30 tons of the stuff could be its size reactor processing! To do so is impressive ) its use assumes ClF3 is a spontaneous product of some.! Eget leo id, massa felis diam quis, vulputate, Donec November, and much...
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